Unexpected Propargylic Retro-Brook Rearrangements in Alkynes

Wang, X; Gao, Q; Buevich, AV; Yasuda, N; Zhang, YL; Yang, RS; Zhang, LK; Martin, GE; Williamson, RT

Wang, X (reprint author), Merck & Co Inc, Analyt Res & Dev Rahway, Kenilworth, NJ 07033 USA.; Gao, Q (reprint author), Merck & Co Inc, Analyt Res & Dev Kenilworth, Kenilworth, NJ 07033 USA.

JOURNAL OF ORGANIC CHEMISTRY, 2019; 84 (16): 10024

Abstract

Retro-Brook rearrangements refer to the intramolecular migration of a silyl group from oxygen to carbon. In this study, we report a novel propargylic ......

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