Fluorium-Initiated Dealkylative Cyanation of Thioethers to Thiocyanates

Chen, Y; Qi, HY; Chen, N; Ren, DM; Xu, JX; Yang, ZH

Xu, JX; Yang, ZH (reprint author), Beijing Univ Chem Technol, Fac Sci, Dept Organ Chem, State Key Lab Chem Resource Engn, Beijing 100029, Peoples R China.

JOURNAL OF ORGANIC CHEMISTRY, 2019; 84 (14): 9044

Abstract

Thioethers are converted to thiocyanates via fluorium-initiated dealkylative cyanation. Selectfluor is used as the oxidant, and trimethylsilyl cyanide......

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