Intercepting the Disilene-Silylsilylene Equilibrium

Stanford, MW; Schweizer, JI; Menche, M; Nichol, GS; Holthausen, MC; Cowley, MJ

Cowley, MJ (reprint author), Univ Edinburgh, Sch Chem, Joseph Black Bldg,David Brewster Rd, Edinburgh EH9 3FJ, Midlothian, Scotland.; Holthausen, MC (reprint author), Goethe Univ, Inst Anorgan Chem, Max von Laue Str 7, D-60438 Frankfurt, Germany.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2019; 58 (5): 1329

Abstract

The equilibrium between disilenes (R2Si=SiR2) and their silylsilylene (R3Si=SiR) isomers has previously been inferred but not directly observed, excep......

Full Text Link