Rhodium-Catalyzed C-H Activation-Based Construction of Axially and Centrally Chiral Indenes through Two Discrete Insertions

Wang, F; Jing, JR; Zhao, YL; Zhu, XH; Zhang, XP; Zhao, LJ; Hu, PJ; Deng, WQ; Li, XW

Li, XW (corresponding author), Shaanxi Normal Univ SNNU, Sch Chem & Chem Engn, Xian 710062, Peoples R China.; Li, XW (corresponding author), Shandong Univ, Inst Frontier & Interdisciplinary Sci, Inst Mol Sci & Engn, Qingdao 266237, Peoples R China.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2021; 60 (30): 16628

Abstract

Reported herein is asymmetric [3+2] annulation of arylnitrones with different classes of alkynes catalyzed by chiral rhodium(III) complexes, with the ......

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