Elusive Valence Transition in Mixed-Valence Sesquioxide Cs4O6

Colman, RH; Okur, HE; Kockelmann, W; Brown, CM; Sans, A; Felser, C; Jansen, M; Prassides, K

Prassides, K (reprint author), Osaka Prefecture Univ, Grad Sch Engn, Dept Mat Sci, Osaka 5998531, Japan.; Prassides, K (reprint author), Tohoku Univ, Adv Inst Mat Res WPI AIMR, Sendai, Miyagi 9808577, Japan.

INORGANIC CHEMISTRY, 2019; 58 (21): 14532

Abstract

Cs4O6 is a mixed-valence molecular oxide with a cubic structure, comprising valency-delocalized O-2(4/3-) units and with properties highly sensitive t......

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