Metal-Free Synthesis of Poly(silyl ether)s under Ambient Conditions

Sample, CS; Lee, SH; Bates, MW; Ren, JM; Lawrence, J; Lensch, V; Gerbec, JA; Bates, CM; Li, SG; Hawker, CJ

Li, SG; Hawker, CJ (reprint author), Univ Calif Santa Barbara, Dept Chem & Biochem, Mat Dept, Mitsubishi Chem Ctr Adv Mat, Santa Barbara, CA 93106 USA.; Li, SG; Hawker, CJ (reprint author), Univ Calif Santa Barbara, Mat Res Lab, Santa Barbara, CA 93106 US

MACROMOLECULES, 2019; 52 (5): 1993

Abstract

Metal-free hydrosilylation using tris(pentafluorophenyl)borane (B(C6F5)(3)) as a catalyst enables the rapid polymerization of alpha-diketone and bis(s......

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