Bronsted Acid Catalyzed 1,2-Silyl Shift in Propargyl Silanes: Synthesis of Silyl Dienes and Silyl Indenes

Purins, M; Mishnev, A; Turks, M

Turks, M (reprint author), Riga Tech Univ, Fac Mat Sci & Appl Chem, Inst Technol Organ Chem, Paula Valdena Str 3, LV-1048 Riga, Latvia.

JOURNAL OF ORGANIC CHEMISTRY, 2019; 84 (6): 3595

Abstract

A general method for generation of allyl carbenium ions from propargyl silanes via a 1,2-silyl shift by Bronsted acids is reported. Two possible react......

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