Trans-1,4-stereospecific copolymerization of isoprene and butadiene catalyzed by TiCl4/MgCl2 Ziegler-Natta catalyst: III Effect of alkylaluminium on monomer reactivity ratios

Niu, QT; Zhang, JY; He, AH

He, AH (corresponding author), Qingdao Univ Sci & Technol, Sch Polymer Sci & Engn, Shandong Prov Key Lab Olefin Catalysis & Polymeri, Key Lab Rubber Plast,Minist Educ, Qingdao 266042, Shandong, Peoples R China.

POLYMER INTERNATIONAL, 2021; 70 (10): 1449

Abstract

Copolymerizations of isoprene (Ip) and butadiene (Bd) in different Bd/Ip feed ratios were carried out using the heterogeneous TiCl4/MgCl2 type Ziegler......

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