Cationic Phosphinidene as a Versatile P1 Building Block: [LC-P]+ Transfer from Phosphonio-Phosphanides [LC-P-PR3]+ and Subsequent LC Replacement Reactions (LC = N-Heterocyclic Carbene)

Royla, P; Schwedtmann, K; Han, ZY; Fidelius, J; Gates, DP; Gomila, RM; Frontera, A; Weigand, JJ

Weigand, JJ (通讯作者),Tech Univ Dresden, Fac Chem & Food Chem, Chair Inorgan Mol Chem, D-01069 Dresden, Germany.;Gates, DP (通讯作者),Univ British Columbia, Dept Chem, Vancouver, BC V6T 1Z1, Canada.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2023; 145 (18): 10364

Abstract

Cationic imidazoliumyl(phosphonio)-phosphanides [LC-P-PR3]+ (1a-e+, LC = 4,5-dimethyl-1,3-diisopropylimidazolium-2-yl; R = alkyl, aryl) are obtained v......

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