Synthesis and catalytic activity of N-heterocyclic silylene (NHSi) iron (II) hydride for hydrosilylation of aldehydes and ketones

Du, XY; Qi, XH; Li, K; Li, XY; Sun, HJ; Fuhr, O; Fenske, D

Sun, HJ (corresponding author), Shandong Univ, Sch Chem & Chem Engn, Key Lab Special Funct Aggregated Mat, Minist Educ, Shanda Nanlu 27, Jinan 250100, Peoples R China.

APPLIED ORGANOMETALLIC CHEMISTRY, 2021; 35 (8):

Abstract

A novel silylene supported iron hydride [Si, C]FeH (PMe3)(3) (1) was synthesized by C (sp(3))-H bond activation with zero-valent iron complex Fe (PMe3......

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