Metal Ion-Terpyridine-Functionalized L-Tyrosinamide Aptamers: Nucleoapzymes for Oxygen Insertion into C-H Bonds and the Transformation of L-Tyrosinamide into Amidodopachrome

Luo, GF; Biniuri, Y; Vazquez-Gonzalez, M; Wulf, V; Fadeev, M; Lavi, R; Willner, I

Willner, I (reprint author), Hebrew Univ Jerusalem, Minerva Ctr Biohybrid Complex Syst, Inst Chem, IL-91904 Jerusalem, Israel.

ADVANCED FUNCTIONAL MATERIALS, 2019; 29 (33):

Abstract

A series of metal ion-terpyridine-modified L-tyrosinamide aptamers (M-n(+) = Cu2+ or Fe3+) act as enzyme-mimicking catalysts (nucleoapzymes) for oxyge......

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