Unprecedented Formation of a Binuclear Au(II)-Au(II) Complex through Redox State Cycling: Electrochemical Interconversion of Au(I)-Au(I), Au(II)-Au(II), and Au(I)-Au(III) in Binuclear Complexes Containing the Carbanionic Ligand C6F4PPh2

Sun, CC; Mirzadeh, N; Guo, SX; Li, JZ; Li, ZK; Bond, AM; Zhang, J; Bhargava, SK

Bond, AM; Zhang, J (reprint author), Monash Univ, Sch Chem, Clayton, Vic 3800, Australia.; Mirzadeh, N; Bhargava, SK (reprint author), RMIT Univ, Sch Sci, GPO Box 2476, Melbourne, Vic 3001, Australia.

INORGANIC CHEMISTRY, 2019; 58 (20): 13999

Abstract

The rational design of binuclear Au(I)-Au(I), Au(II)-Au(II), and Au(I)-Au(III) complexes requires an understanding of how the redox states interconver......

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