Unveiling the Local Structure of Cu2+ Ions from d-Orbital Splitting. Application to K2ZnF4:Cu2+ and KZnF3:Cu2+

Rodriguez, F

Rodriguez, F (reprint author), Univ Cantabria, Fac Ciencias, MALTA Consolider Team, Earth Sci & Condensed Matter Phys Dept DCITIMAC, E-39005 Santander, Spain.

INORGANIC CHEMISTRY, 2017; 56 (4): 2029

Abstract

This work investigates why JahnTeller (JT) transition-metal ions like Cu2+ (d9) or Mn3+ (d4) with octahedral coordination exhibit low-symmetry distort......

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