Accessing the First nido-Carborane-Substituted Diphosphetane: A Ligand and Synthon for nido-Carboranylphosphanes

Coburger, P; Bielytskyi, P; Williamson, D; Rys, E; Kreienbrink, A; Lnnecke, P; Matysik, J; Hey-Hawkins, E

Hey-Hawkins, E (reprint author), Univ Leipzig, Fac Chem & Mineral, Inst Inorgan Chem, Johannisallee 29, D-04103 Leipzig, Germany.

CHEMISTRY-A EUROPEAN JOURNAL, 2019; 25 (49): 11456

Abstract

Deboronation of a carborane-substituted diphosphetane 2 in toluene yielded the first nido-carboranyldiphosphetane 1. The P-P bond in 1 can be broken v......

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