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Mn-Catalyzed Electrooxidative Undirected C-H/P-H Cross-Coupling between Aromatics and Diphenyl Phosphine Oxides

期刊: ACS CATALYSIS, 2021; 11 (7)

C-P bonds are widely found in a great many bioactive compounds and functional molecules. Transition-metal-catalyzed dehydrogenative C-H/P-H cross-coup......

Ligand-Controlled Ni(0)-Al(III) Bimetal-Catalyzed C3-H Alkenylation of 2-Pyridones by Reversing Conventional Selectivity

期刊: ACS CATALYSIS, 2021; 11 (8)

Conventional C-H alkenylation with alkynes via low-valent transition-metal catalysis occurs at the C6 or C4 position of 2-pyridone with electron-defic......

Fine-Tuning Radical/Nonradical Pathways on Graphene by Porous Engineering and Doping Strategies

期刊: ACS CATALYSIS, 2021; 11 (8)

Nitrogen and sulfur co-doped graphene (N,S-G) is activated using ZnCl2, KOH, and CO2 to develop different defects and functionalities. The modified ca......

Regioselective Intermolecular Hydroamination of Unactivated Alkenes: "Co-H" Enabled Remote Functionalization

期刊: ACS CATALYSIS, 2021; 11 (11)

The Co-H-catalyzed intermolecular hydroamination of unactivated alkenes with various amine electrophiles was achieved by introducing a removable direc......

Pd-Catalyzed Redox Divergent Coupling of Ketones with Terpenols

期刊: ACS CATALYSIS, 2021; 11 (12)

Redox diversity is a common and important feature of nature. Herein, a Pd-catalyzed redox divergent coupling of ketones with terpenols has been develo......

Origin of Water-Induced Deactivation of MnO2-Based Catalyst for Room-Temperature NO Oxidation: A First-Principles Microkinetic Study

期刊: ACS CATALYSIS, 2021; 11 (12)

MnO2-based catalysts exhibit remarkable activities in a room-temperature NO oxidation reaction (RT-NOR) but are challenged by water-induced deactivati......

Enantioselective Nickel-Catalyzed Hydrocyanative Desymmetrization of Norbornene Derivatives

期刊: ACS CATALYSIS, 2021; 11 (12)

A nickel-catalyzed enantioselective hydrocyanation of N-aryl 5-norbornene-endocis-2,3-dicarboximides was reported. This desymmetrization process allow......

Palladium-Catalyzed C(sp(3))-H Arylation and Alkynylation of Peptides Directed by Aspartic Acid (Asp)

期刊: ACS CATALYSIS, 2021; 11 (12)

Modification of the aliphatic residues without an apparent functional handle has attracted broad attention, and the scientists anticipate that the C(s......

Unconventional High-Index Facet of Iridium Boosts Oxygen Evolution Reaction: How the Facet Matters

期刊: ACS CATALYSIS, 2021; 11 (13)

Iridium (Ir) nanostructures with well-defined shapes, and particularly, highly active surface, are attractive for the application of electrocatalytic ......

Unraveling the Intermediate Reaction Complexes and Critical Role of Support-Derived Oxygen Atoms in CO Oxidation on Single-Atom Pt/CeO2

期刊: ACS CATALYSIS, 2021; 11 (14)

CeO2-supported Pt single-atom catalysts have been extensively studied due to their relevance in automobile emission control and for the fundamental un......

Synergistic Catalysis of Al and Zn Sites of Spinel ZnAl2O4 Catalyst for CO Hydrogenation to Methanol and Dimethyl Ether

期刊: ACS CATALYSIS, 2021; 11 (15)

Activation and surface reactions of CO and H-2 on spinel ZnAl2O4 catalyst under CO hydrogenation reaction conditions were studied using temperature-pr......

Liquid Metal Shell as an Effective Iron Oxide Modifier for Redox-Based Hydrogen Production at Intermediate Temperatures

期刊: ACS CATALYSIS, 2021; 11 (16)

This study reports molten metals (bismuth, indium, and tin) as effective modifiers for iron-based redox catalysts in the context of chemical looping-b......

An Ingenious Strategy to Integrate Multiple Electrocatalytically Active Components within a Well-Aligned Nitrogen-Doped Carbon Nanotube Array Electrode for Electrocatalysis

期刊: ACS CATALYSIS, 2021; 11 (7)

In this paper, an ingenious strategy was developed to construct a well-aligned nitrogen-doped carbon nanotube (NCNT) array electrode integrated with m......

Ferrocene-Functionalized Polyoxo-Titanium Cluster for CO2 Photoreduction

期刊: ACS CATALYSIS, 2021; 11 (8)

It is well-known that effective charge transfer within the catalyst structure is critical to the improvement of the performance of catalytic reaction.......

Preferential Growth of the Cobalt (200) Facet in Co@N-C for Enhanced Performance in a Fenton-like Reaction

期刊: ACS CATALYSIS, 2021; 11 (9)

Herein, a series of Co@N-C materials are synthesized using nitrates LiNO3, NaNO3, and KNO3) as templates to control the preferential growth of the cob......

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